They are used as high-current switches or , where contact erosion from constant cycling would be a problem for conventional relay contacts.
Owing to environmental considerations about the mercury toxicity, mercury relays are mostly obsolete, though modern encapsulated units still have applications. They are generally being replaced by solid state relays.
Around the top part of the tube is placed the Solenoid. When energised, this coil attracts the slug, lifting it upwards and out of the mercury pool. The mercury is no longer displaced, and thus flows downwards, away from the upper contact, and so the circuit opens. This allows for normally closed operation.
For the more traditional normally open relay operation, the side contact is arranged somewhat higher up (or the volume of mercury is reduced), so that contact is not made when the iron slug is freely floating on the pool of mercury. The control coil is mounted below the rest level of the slug, and when energised draws down the slug deeper into the pool, thereby displacing additional mercury and thus raising the level to the previously uncovered side contact and closing the circuit.Vladimir Gurevich, Electric Relays: Principles and Applications CRC Press, 2005 Section 3.12 "Mercury displacement relays"
The mercury relay thus allows for switching of higher currents with a small control current, for a large number of cycles. They are often installed into automatic controllers that required extended periods of unattended continuous switching operation. The mercury surface is self-restoring after an arc, and the contact resistance is low and stable.
The glass tube of a mercury relay must be mounted near-vertically. The sensitivity of these relays can be altered by adjusting their angle relative to vertical. As sensitivity depends upon angle, they are unsuitable for use on mobile equipment or with conditions of high vibration.
For high-speed use, the mercury-wetted relay is used instead. This combines the speed of a low-mass relay, together with the fast wetting of mercury contacts. A relay, usually a reed relay, has its contacts coated with a small quantity of mercury. This gives the low bounce advantage of mercury, although the current capacity is still limited to broadly that of the original reed relay.
Impulse relays
High-speed operation
Other mercury switching devices
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